Unpair watch without iPhone

If you already gave away your Apple Watch, you can erase and turn off Activation Lock from iCloud.com. Here's how:

1. On a computer, go to Find My iPhone on iCloud.com and sign in with your Apple ID. 
2. Select All Devices, then click your Apple Watch.
3. Click Erase Apple Watch. Select Next until the device is erased.
4. Click the X button  next to your Apple Watch. 

Learn more about Activation Lock. 

See "Erase your Apple Watch" here.

Unpair and erase your Apple Watch - Apple Support